Telomerization Initiated by Nickel Peroxide
نویسندگان
چکیده
منابع مشابه
Kinetic study of nickel-thiolate oxygenation by hydrogen peroxide. Implications for nickel-containing superoxide dismutase.
The rate of metal-thiolate oxygenation by hydrogen peroxide has been measured for a model complex of nickel-containing superoxide dismutase (NiSOD) as 0.47 ± 0.03 M(-1) s(-1) at 303 K. Under typical synthetic conditions the reaction proceeds within seconds yielding S-oxygenate products. At biologically relevant H(2)O(2) concentrations, half-life times extend to several hours or days. The result...
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1962
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.65.7_1044